Number of the records: 1
Reintroducing Azidodifluoromethane: Synthesis, Stability and [3+2] Cycloadditions
- 1.0495299 - ÚOCHB 2019 RIV DE eng J - Journal Article
Voltrová, Svatava - Putovný, Igor - Matoušek, V. - Klepetářová, Blanka - Beier, Petr
Reintroducing Azidodifluoromethane: Synthesis, Stability and [3+2] Cycloadditions.
European Journal of Organic Chemistry. Roč. 2018, č. 37 (2018), s. 5087-5090. ISSN 1434-193X. E-ISSN 1099-0690
Institutional support: RVO:61388963
Keywords : fluorinated compounds * azides * fluorine * difluoromethyl group * triazoles * synthetic methods
OECD category: Organic chemistry
Impact factor: 3.029, year: 2018
Azidodifluoromethane was prepared in 65% yield from chlorodifluoromethane by a two-step synthesis using tributyl(difluoromethyl)ammonium chloride as an intermediate. The resulting azide was used in Huisgen azide-alkyne reactions and ketone [3+2] cycloadditions to access novel N-difluoromethyl-1,2,3-triazoles.
Permanent Link: http://hdl.handle.net/11104/0288883
Number of the records: 1