Various types of non-covalent interactions contributing towards crystal packing of halogenated diphospha-dicarbaborane with an open pentagonal belt

0491032 - ÚACH 2019 RIV GB eng J - Journal Article
Holub, Josef - Růžičková, Z. - Hobza, Pavel - Fanfrlík, Jindřich - Hnyk, Drahomír - Růžička, A.
Various types of non-covalent interactions contributing towards crystal packing of halogenated diphospha-dicarbaborane with an open pentagonal belt.
New Journal of Chemistry. Roč. 42, č. 13 (2018), s. 10481-10483. ISSN 1144-0546. E-ISSN 1369-9261
R&D Projects: GA ČR(CZ) GA17-08045S
Institutional support: RVO:61388980 ; RVO:61388963
Keywords : halogenated diphospha-dicarbaborane * bond
OECD category: Inorganic and nuclear chemistry; Physical chemistry (UOCHB-X)
Impact factor: 3.069, year: 2018

We have prepared 3-Cl-10-I-nido-7,8,9,11-P2C2B7H7by the reaction of 3-Cl-nido-7,8,9,11-P2C2B7H8with I2in the presence of AlCl3. The product was obtained in a yield of 49% and was characterized by NMR spectroscopy and X-ray crystallography. Quantum chemical calculations have demonstrated that the crystal structure is stabilized by hydrogen, dihydrogen and pnictogen bonds.
Permanent Link: http://hdl.handle.net/11104/0285109


Research data: RSC publishing