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Homo- and Copolycyclotrimerization of Aromatic Internal Diynes Catalyzed with Co-2(CO)(8): A Facile Route to Microporous Photoluminescent Polyphenylenes with Hyperbranched or Crosslinked Architecture
- 1.0488694 - ÚFCH JH 2019 RIV DE eng J - Journal Article
Sedláček, J. - Sokol, J. - Zedník, J. - Faukner, T. - Kubů, Martin - Brus, Jiří - Trhlíková, Olga
Homo- and Copolycyclotrimerization of Aromatic Internal Diynes Catalyzed with Co-2(CO)(8): A Facile Route to Microporous Photoluminescent Polyphenylenes with Hyperbranched or Crosslinked Architecture.
Macromolecular Rapid Communications. Roč. 39, č. 4 (2018), č. článku 1700518. ISSN 1022-1336. E-ISSN 1521-3927
Institutional support: RVO:61388955 ; RVO:61389013
Keywords : microporous polymers * photoluminescence * polycyclotrimerization * polyphenylenes
OECD category: Physical chemistry; Physical chemistry (UMCH-V)
Impact factor: 4.078, year: 2018
This study reports the first Co-2(CO)(8)-catalyzed [2+2+2] polycyclotrimerization by the transformation of internal ethynyl groups of aromatic diyne monomers. The reaction yields polycyclotrimers of polyphenylene-type with either hyperbranched or partly crosslinked architecture. The homopolycyclotrimerization of the monomers with two ethynyl groups per one molecule, namely 1,4-bis(phenylethynyl)benzene, 4,4-bis(phenylethynyl)biphenyl, and 4-(phenylethynyl)phenylacetylene, gives partly crosslinked, insoluble polyphenylenes. The soluble, hyperbranched polyphenylenes are generated via copolycyclotrimerization of 1,4-bis(phenylethynyl)benzene with 1,2-diphenylacetylene (average number of ethynyl groups per monomer molecule < 2). This one-step polycyclotrimerization path to hyperbranched or partly crosslinked polyphenylenes is an alternative to the synthesis of these polymers by Diels-Alder transformation of substituted cyclopentadienones. All polyphenylenes prepared exhibit photoluminescence with emission maxima ranging from 381 to 495 nm. Polyphenylenes with a less compact packing of segments are microporous (specific surface area up to 159 m(2) g(-1)), which is particularly important in the case of soluble polyphenylenes because they can be potentially used to prepare microporous layers.
Permanent Link: http://hdl.handle.net/11104/0283240
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