0488574 - ÚCHP 2019 RIV NL eng J - Journal Article
Vajglová, Zuzana - Kumar, N. - Eränen, K. - Tokarev, A. - Peurla, M. - Peltonen, J. - Murzin, D.Yu. - Salmi, T.
Influence of the Support of Copper Catalysts on Activity and 1,2-dichloroethane Selectivity in Ethylene Oxychlorination.
Applied Catalysis A - General. Roč. 556, APR 25 (2018), s. 41-51. ISSN 0926-860X. E-ISSN 1873-3875
Institutional support: RVO:67985858
Keywords : oxychlorination * copper * support effect
OECD category: Chemical process engineering
Impact factor: 4.630, year: 2018

Five different support materials were modified with 5 wt.% Cu, using an evaporation impregnation method. The synthesized CuCl2/gama-Al2O3, CuCl2/TiO2 (Hombikat), CuCl2/TiO2 (Alfa Aesar), CuCl2/SiO2 and CuCl2/H-Beta-25 materials were characterized by nitrogen physisorption, X-ray powder diffraction, scanning electron microscopy, energy dispersive Xray microanalysis, transmission electron microscopy, Fourier transform infrared spectroscopy and CO2-temperature programmed desorption. The physical-chemical characterization was correlated with catalytic activity, stability and selectivity in the ethylene oxychlorination. It was found that gama-Al2O3 and TiO2 support materials demonstrate very good activity and 1,2dichloroethane selectivity compare to other catalysts. Zeolite H-Beta-25 and SiO2 support materials proved to be unusable for this reaction.
Permanent Link: http://hdl.handle.net/11104/0284033