Catalytic performance of advanced titanosilicate selective oxidation catalysts – a review

0488454 - ÚFCH JH 2019 RIV NL eng J - Journal Article
Přech, Jan
Catalytic performance of advanced titanosilicate selective oxidation catalysts – a review.
Catalysis Reviews-Science and Engineering. Roč. 60, č. 1 (2018), s. 71-131. ISSN 0161-4940. E-ISSN 1520-5703
R&D Projects: GA ČR GBP106/12/G015
Institutional support: RVO:61388955
Keywords : Epoxidation * hydrogen peroxide * selective oxidation * titanosilicate * zeolite
OECD category: Physical chemistry
Impact factor: 9.000, year: 2018

This review article aims to cover the state-of-the-art of titanosilicate catalysts for selective oxidations developed within past seven years. Many elaboratedmaterials (e. g., layered and pillared titanosilicates, hierarchical composite materials, and others) have been prepared and thoroughly characterized. However, their catalytic properties have been usually investigated only using a single or few model substrates and compared with a benchmarking material. The main goal of this article is to summarize the novel catalysts and compare their catalytic performance with each other. The comparison is focused on epoxidation. In addition, phenol hydroxylation and sulphide oxidation are briefly covered.
Permanent Link: http://hdl.handle.net/11104/0283761