Rheology of poly(vinyl butyral) solution containing fumed silica in correlation with electrospinning

0483383 - ÚH 2019 RIV CN eng J - Journal Article
Peer, Petra - Polášková, M. - Šuly, P.
Rheology of poly(vinyl butyral) solution containing fumed silica in correlation with electrospinning.
Chinese Journal of Polymer Science. Roč. 36, č. 6 (2018), s. 742-748. ISSN 0256-7679. E-ISSN 1439-6203
R&D Projects: GA ČR GA17-26808S
Grant - others:Ministerstvo školství, mládeže a tělovýchovy (MŠMT)(CZ) LO1504
Institutional support: RVO:67985874
Keywords : electrospinning * nanofibres * polyvinyl butyral * fumed silica * rheology
OECD category: Polymer science
Impact factor: 2.804, year: 2018

The rheological properties in question are influenced by many factors, ranging from the characteristics of the given polymer or solvent to the flowing conditions. The primary focus of this study is to analyse the rheological behaviour of polyvinyl butyral-Mowital B 60H-(PVB) solutions dissolved in methanol and a blend of these with fumed silica nanoparticles. The preparation of the nanofibrous web and the quality of nanofibres were correlated with the rheology of the polymer solution. It was discerned that drastically intensifying shear viscosity and the elasticity of the solution exerted a negligible effect on the formation of fibres, a finding which has rarely been discussed in the literature. The morphologies and structures of the PVB/silica nanofibrous membranes were investigated by scanning electron microscopy, and by utilizing a thermogravimetric analyser and a Fourier transform infrared spectrometer.
Permanent Link: http://hdl.handle.net/11104/0284623