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Potential-driven On/Off Switch Strategy for the Electrosynthesis of [7]Helicene-derived Polymers.
- 1.0482227 - ÚCHP 2018 MY eng C - Conference Paper (international conference)
Storch, Jan - Žádný, Jaroslav - Strašák, Tomáš - Hrbáč, J. - Fekete, Ladislav - Pokorný, Jan - Bulíř, Jiří - Vacek, J.
Potential-driven On/Off Switch Strategy for the Electrosynthesis of [7]Helicene-derived Polymers.
Souvenir Programme. -: -, 2017. ISBN N.
[POLYCHAR 2017 World Forum on Advanced Materials /25./. Kuala Lumpur (MY), 09.10.2017-13.10.2017]
R&D Projects: GA MPO FV10082
Institutional support: RVO:67985858
Keywords : helicene * anodic reaction * electropolymerization
OECD category: Organic chemistry; Physical chemistry (FZU-D)
3-([7]Helicen-9-yl)-thiophene hybrid monomer was electrooxidized in acetonitrile by cyclic voltammetry with anodic potential limits of +1.5 V or +2.5 V, resulting in a conductive and non-conductive polymer, respectively. The electrochemical findings were supplemented by microscopy investigations; UV-Vis, fluorescence and vibrational spectroscopies, ellipsometry measurements and computational chemistry. The electrodeposited polymers could be used for the further development of materials applicable in organic electronics and sensing technologies.
Permanent Link: http://hdl.handle.net/11104/0277609
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