Intercalation of model aminopyridine push – pull molecules into layered phosphates and phosphonates.

0479330 - ÚMCH 2018 CZ eng A - Abstract
Melánová, Klára - Zima, Vítězslav - Svoboda, J. - Beneš, L. - Bureš, F. - Kutálek, P.
Intercalation of model aminopyridine push – pull molecules into layered phosphates and phosphonates.
Workshop on Layered Materials. Praha: ÚFCh AV ČR, v. v. i., 2017. Po11. ISBN 978-80-87351-45-1.
[Workshop on Layered Materials. 01.09.2017-05.09.2017, Třešť]
Institutional support: RVO:61389013
Keywords : intercalation * push - pull molecules * aminopyridine
Subject RIV: CA - Inorganic Chemistry

Intercalates of five model NLO-active molecules having pyridine-4-yl moieties into three different layered phosphates and phosphonates (α-Zr(HPO4)2·H2O, γ-Ti(HPO4)2·2H2O and zirconium sulfophenylphosphonate) were prepared and characterized. The influence of the number of protonable atoms in the molecule and its shape on the amount of the guest molecules intercalated, their arrangement and especially on optical properties of the intercalates is discussed.
Permanent Link: http://hdl.handle.net/11104/0277145