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The effect of nanoparticle nonuniformity on the ratio of gyration and hydrodynamic radiuses

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    0471429 - ÚMCH 2017 RIV US eng J - Journal Article
    Kratochvíl, Pavel - Netopilík, Miloš
    The effect of nanoparticle nonuniformity on the ratio of gyration and hydrodynamic radiuses.
    International Journal of Polymer Analysis and Characterization. Roč. 22, č. 2 (2017), s. 112-117. ISSN 1023-666X. E-ISSN 1563-5341
    R&D Projects: GA ČR(CZ) GA13-02938S
    Grant - others:OPPK(XE) CZ.2.16/3.1.00/24504; AV ČR(CZ) ASRT-16-02
    Program: Bilaterální spolupráce
    Institutional support: RVO:61389013
    Keywords : diffusion coefficient * nanoparticles * nonuniformity correction
    OECD category: Polymer science
    Impact factor: 1.333, year: 2017

    The ratio of the radius of gyration, obtained by static light scattering, and the hydrodynamic radius, obtained by dynamic light scattering, are routine experimental techniques for the assessment of nanoparticle shape. The potential effect of particle nonuniformity is mostly not considered. In this communication, we demonstrate that, even with medium particle nonuniformities, it is advisable to apply appropriate corrections. The values of the correction factors are offered in a diagram for various particle shapes, and two types of particle-size distributions and their widths.
    Permanent Link: http://hdl.handle.net/11104/0269261

     
     
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