Frustrated Lewis pairs-assisted reduction of carbonyl compounds

0470824 - ÚOCHB 2017 CZ eng C - Conference Paper (international conference)
Marek, Aleš - Pedersen, M. H. F.
Frustrated Lewis pairs-assisted reduction of carbonyl compounds.
Proceedings of the 4th International Conference on Chemical Technology. Prague: Czech Society of Industrial Chemistry, 2016 - (Veselý, M.; Hrdlička, Z.; Hanika, J.; Lubojacký, J.), s. 534-538. ICCT. ISBN 978-80-86238-94-4. ISSN 2336-811X. E-ISSN 2336-8128.
[International Conference on Chemical Technology (ICCT) /4./. Mikulov (CZ), 25.04.2016-27.04.2016]
Institutional support: RVO:61388963
Keywords : carbonyl compounds * frustrated Lewis parts * alcohol synthesis
Subject RIV: CC - Organic Chemistry

An alternative and robust method for the reduction of carbonyl groups by frustrated Lewis pairs (FLPs) is reported in this paper. With its very mild reaction conditions, good to excellent yields, absolute regioselectivity and the non-metallic character of the reagent, it provides an excellent tool for 1H, 2H as well as 3H chemistry. It is a new strategy for the one-pot synthesis of aromatic alcohols selectively labeled with heavy isotopes of hydrogen.
Permanent Link: http://hdl.handle.net/11104/0268449