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Self-assembly of organocyanide dianions and metal–organic macrocycles into polymeric architectures including an unprecedented quadruple helical aperiodic structure\n

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    0467689 - FZÚ 2017 RIV US eng J - Journal Article
    Zhang, X. - Zhao, H. - Palatinus, Lukáš - Gagnon, K.J. - Bacsa, J. - Dunbar, K.R.
    Self-assembly of organocyanide dianions and metal–organic macrocycles into polymeric architectures including an unprecedented quadruple helical aperiodic structure
    .
    Crystal Growth & Design. Roč. 16, č. 4 (2016), s. 1805-1811. ISSN 1528-7483. E-ISSN 1528-7505
    Institutional support: RVO:68378271
    Keywords : crystal engineering * self-assembled polymer * modulated structure * helical chain
    Subject RIV: CC - Organic Chemistry
    Impact factor: 4.055, year: 2016

    The conformations of organocyanide dianions and the competing supramolecular interactions have been found to be critical for the different structures of one-dimensional coordination polymers in the self-assembly of metal−organic macrocyclic complexes and organocyanide dianions. The flexible 1,3-dicyanamidobenzene dianions forms an aperiodic quadruple helical structure but only zigzag chains when water is present.

    Permanent Link: http://hdl.handle.net/11104/0265741

     
     
Number of the records: 1  

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