Number of the records: 1
Synthesis of inherently chiral calixarenes via direct mercuration of the partial cone conformation
- 1.0460528 - FZÚ 2017 RIV GB eng J - Journal Article
Slavík, P. - Kohout, M. - Böhm, S. - Eigner, Václav - Lhoták, P.
Synthesis of inherently chiral calixarenes via direct mercuration of the partial cone conformation.
Chemical Communications. Roč. 52, č. 11 (2016), s. 2366-2369. ISSN 1359-7345. E-ISSN 1364-548X
R&D Projects: GA ČR GA15-12653S
Institutional support: RVO:68378271
Keywords : calix[4]arene * mercuration * brigding * X-ray crystallography * Jana2006
Subject RIV: CC - Organic Chemistry
Impact factor: 6.319, year: 2016
Direct mercuration of calix[4]arene immobilized in the partial cone conformation led to the meta-substituted isomer which was subsequently subjected to Pd-catalysed coupling (C–H activation) with the neighbouring aromatic subunit. Regioselective mercuration thus enabled access to a novel type of inherently chiral calixarenes with a highly distorted cavity potentially applicable to the design of new chiral receptors.
Permanent Link: http://hdl.handle.net/11104/0261787
Number of the records: 1