Modular Approach to Heterogenous Catalysis. Manipulation of Cross-Coupling Catalyst Activity

0458443 - ÚOCHB 2017 RIV US eng J - Journal Article
Štibingerová, Iva - Voltrová, Svatava - Kočová, Šárka - Lindale, M. - Šrogl, Jiří
Modular Approach to Heterogenous Catalysis. Manipulation of Cross-Coupling Catalyst Activity.
Organic Letters. Roč. 18, č. 2 (2016), s. 312-315. ISSN 1523-7060. E-ISSN 1523-7052
R&D Projects: GA MŠMT LH12012
Institutional support: RVO:61388963
Keywords : polysiloxane gels * Suzuki coupling * palladium nanoparticles
Subject RIV: CC - Organic Chemistry
Impact factor: 6.579, year: 2016

A new type of robust, heterogeneous, modular Pd catalyst with metal embedded in the gel matrix is presented. The regulatory element of its catalytic activity has been introduced via chemical changes in the gel. The concept is illustrated in a series of Suzuki-Miyaura cross-coupling reactions. The demonstrated catalyst activity variations depend on the structure of the gel.
Permanent Link: http://hdl.handle.net/11104/0258726