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Palladium complexes with 3-phenylpropylamine ligands: synthesis, structures, theoretical studies and application in the aerobic oxidation of alcohols as heterogeneous catalysts
- 1.0456263 - FZÚ 2016 RIV GB eng J - Journal Article
Karami, K. - Naeini, N.H. - Eigner, Václav - Dušek, Michal - Lipkowski, J. - Hervés, P. - Tavakol, H.
Palladium complexes with 3-phenylpropylamine ligands: synthesis, structures, theoretical studies and application in the aerobic oxidation of alcohols as heterogeneous catalysts.
RSC Advances. Roč. 5, č. 124 (2015), s. 102424-102435. E-ISSN 2046-2069
R&D Projects: GA ČR GA15-12653S
Institutional support: RVO:68378271
Keywords : single-crystal structure analysis * paladium complex * aerobic oxidation
Subject RIV: CC - Organic Chemistry
Impact factor: 3.289, year: 2015
The reaction of 3-phenylpropylamine with Pd(OAc)2 by heating in toluene resulted in the nearly squareplanar complex trans-[Pd(C6H5(CH2)3NH2)2(OAc)2] (1). Complex 1 reacted with NaCl in methanol to obtain the corresponding product trans-[Pd(C6H5(CH2)3NH2)2Cl2] (2). Treatment of 2 with triphenylphosphine in dichloromethane afforded trans-[Pd(C6H5(CH2)3NH2)2(PPh3)2]2Cl (3). All the palladium(II) complexes (1–3) were fully characterized by IR and NMR spectroscopy. In addition, the crystal structures of 1 and 2 were determined by single-crystal X-ray diffraction analysis.
Permanent Link: http://hdl.handle.net/11104/0256822
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