SnS and SnS2 thin films deposited using a spin-coating technique from intramolecularly coordinated organotin sulfides

0446572 - ÚMCH 2016 RIV GB eng J - Journal Article
Řečica, T. - Střižík, L. - Dostál, L. - Bouška, M. - Vlček, Milan - Beneš, L. - Wágner, T. - Jambor, R.
SnS and SnS2 thin films deposited using a spin-coating technique from intramolecularly coordinated organotin sulfides.
Applied Organometallic Chemistry. Roč. 29, č. 3 (2015), s. 176-180. ISSN 0268-2605. E-ISSN 1099-0739
Institutional support: RVO:61389013
Keywords : organotin sulfide * single - source precursor * spin - coating process
Subject RIV: CA - Inorganic Chemistry
Impact factor: 2.452, year: 2015

Synthesis and applications of organotin(II) sulfide) (1), organotin(II) thiophenolate) (2) and organotin(IV) heptasulfide (3) as potential single-source precursors (SSPs) for the deposition of SnS or SnS2 thin films using a spin-coating method are reported. Compounds 1, 2 and 3 differ either by tin oxidation state or by Sn:S ratio (Sn:S= 2:1 in 1, 1:1 in 2 and 2:7 in 3). It is shown that compound 1 is not a suitable for thin-film fabrication using the spin-coating process because of its incomplete decomposition at annealing temperature. However, compounds 2 and 3 seem to be promising SSPs for spin-coating of amorphous semiconducting thin films of SnS and SnS2, respectively.
Permanent Link: http://hdl.handle.net/11104/0249881