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Ten-vertex dicarbaboranes from nido-5,6-C2B8H12
- 1.0445940 - ÚACH 2016 RIV CH eng J - Journal Article
Štíbr, Bohumil
Ten-vertex dicarbaboranes from nido-5,6-C2B8H12.
Journal of Organometallic Chemistry. Roč. 798, DEC (2015), s. 30-35. ISSN 0022-328X. E-ISSN 1872-8561
R&D Projects: GA ČR(CZ) GAP207/11/0705
Institutional support: RVO:61388980
Keywords : Boron * Carboranes * Dicarbaboranes * Mechanisms
Subject RIV: CA - Inorganic Chemistry
Impact factor: 2.336, year: 2015
The chemistry of the nido-5,6-C2B8H12 dicarbaborane, the most significant compound of the 10-vertex dicarbaborane series, has been discussed in this review within the contexts of reactivity and reaction mechanism. Chemical transformations of this carborane led to the isolation of the whole series of other compounds that now start playing ever increasing role in developing new carborane chemistry. Overviewed are procedures leading to closo and open-structured (nido and arachno) dicarbaboranes together with principles of their substitution on cluster-carbon and boron vertexes.
Permanent Link: http://hdl.handle.net/11104/0247958
Number of the records: 1