The ADOR mechanism for the synthesis of new zeolites

0443988 - ÚFCH JH 2016 RIV GB eng J - Journal Article
Eliášová, Pavla - Opanasenko, Maksym - Wheatley, P. S. - Shamzhy, Mariya - Mazur, Michal - Nachtigall, P. - Roth, Wieslaw Jerzy - Morris, R. E. - Čejka, Jiří
The ADOR mechanism for the synthesis of new zeolites.
Chemical Society Reviews. Roč. 44, č. 20 (2015), s. 7177-7206. ISSN 0306-0012. E-ISSN 1460-4744
R&D Projects: GA ČR GBP106/12/G015; GA ČR(CZ) GP14-30898P
Institutional support: RVO:61388955
Keywords : STRUCTURE-DIRECTING AGENTS * LARGE-PORE ZEOLITES * PILLARED MOLECULAR-SIEVE
Subject RIV: CF - Physical ; Theoretical Chemistry
Impact factor: 34.090, year: 2015

A novel methodology, called ADOR (assembly–disassembly–organisation–reassembly), for the synthesis of zeolites is reviewed here in detail. The ADOR mechanism stems from the fact that certain chemical weakness against a stimulus may be present in a zeolite framework, which can then be utilized for the preparation of new solids through successive manipulation of the material. In this review, we discuss the critical factors of germanosilicate zeolites required for application of the ADOR protocol and describe the mechanism of hydrolysis, organisation and condensation to form new zeolites starting from zeolite UTL. Last but not least, we discuss the potential of this methodology to form other zeolites and the prospects for future investigations.
Permanent Link: http://hdl.handle.net/11104/0246609