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Oxidative Photoredox-Catalytic Activation of Aliphatic Nucleophiles for C(sp3)-C(sp2) Cross-Coupling Reactions
- 1.0437258 - ÚOCHB 2015 RIV DE eng J - Journal Article
Jahn, Emanuela - Jahn, Ullrich
Oxidative Photoredox-Catalytic Activation of Aliphatic Nucleophiles for C(sp3)-C(sp2) Cross-Coupling Reactions.
Angewandte Chemie - International Edition. Roč. 53, č. 49 (2014), s. 13326-13328. ISSN 1433-7851. E-ISSN 1521-3773
Institutional support: RVO:61388963
Keywords : amino acids * cross-coupling * nickel * persistent radical effect * photoredox catalysis
Subject RIV: CC - Organic Chemistry
Impact factor: 11.261, year: 2014
In the light you will find the road (Led Zeppelin): Visible-light photoredox catalysis leads the way in overcoming the reactivity limitations of alkyl nucleophiles in cross-coupling reactions. Iridium-triggered oxidative photoredox activation of alkyltrifluoroborate or carboxylic acids affords alkyl radicals, which undergo nickel-catalyzed cross-coupling reactions.
Permanent Link: http://hdl.handle.net/11104/0240797
Number of the records: 1