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Oxidative Photoredox-Catalytic Activation of Aliphatic Nucleophiles for C(sp3)-C(sp2) Cross-Coupling Reactions

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    0437258 - ÚOCHB 2015 RIV DE eng J - Journal Article
    Jahn, Emanuela - Jahn, Ullrich
    Oxidative Photoredox-Catalytic Activation of Aliphatic Nucleophiles for C(sp3)-C(sp2) Cross-Coupling Reactions.
    Angewandte Chemie - International Edition. Roč. 53, č. 49 (2014), s. 13326-13328. ISSN 1433-7851. E-ISSN 1521-3773
    Institutional support: RVO:61388963
    Keywords : amino acids * cross-coupling * nickel * persistent radical effect * photoredox catalysis
    Subject RIV: CC - Organic Chemistry
    Impact factor: 11.261, year: 2014

    In the light you will find the road (Led Zeppelin): Visible-light photoredox catalysis leads the way in overcoming the reactivity limitations of alkyl nucleophiles in cross-coupling reactions. Iridium-triggered oxidative photoredox activation of alkyltrifluoroborate or carboxylic acids affords alkyl radicals, which undergo nickel-catalyzed cross-coupling reactions.
    Permanent Link: http://hdl.handle.net/11104/0240797

     
     
Number of the records: 1  

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