Alkaline-earth metal phosphonocarboxylates: synthesis, structures, chirality, and luminescence properties

0422324 - ÚMCH 2014 RIV GB eng J - Journal Article
Zima, Vítězslav - Raja, D. S. - Lee, Y. S. - Chang, T. G. - Wu, Ch. Y. - Hu, Ch. Ch. - Lee, K. R. - Lai, J. Y. - Yeh, J. M. - Lin, Ch. H.
Alkaline-earth metal phosphonocarboxylates: synthesis, structures, chirality, and luminescence properties.
Dalton Transactions. Roč. 42, č. 43 (2013), s. 15332-15342. ISSN 1477-9226. E-ISSN 1477-9234
Grant - others:AV ČR(CZ) M200501202
Program: M
Institutional support: RVO:61389013
Keywords : coordination polymers * phosphonates * alkaline-earth
Subject RIV: CA - Inorganic Chemistry
Impact factor: 4.097, year: 2013

Six new alkaline-earth metal carboxyphosphonates with N-(phosphonomethyl)iminodiacetic acid) (H4PMIDA ) and Mg, Sr, and Ba have been synthesized solvothermally in order to study the coordination behavior of H4PMIDA towards alkaline-earth metal ions (Mg2+, Sr2+, and Ba2+) and the structural features of the resulting polymeric compounds. The newly synthesized compounds have been characterized by elemental analysis, UV-Vis spectrometry, IR spectroscopy, thermogravimetry analysis, solid state 31P MAS NMR, powder X-ray diffraction analysis and single crystal X-ray diffraction techniques. The single crystal structure analysis revealed structural variability of the prepared compounds.
Permanent Link: http://hdl.handle.net/11104/0228530