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Acetonyltriphenylphosphonium nitrate
- 1.0398668 - FZÚ 2014 RIV DK eng J - Journal Article
Diop, T. - Diop, L. - Kučeráková, Monika - Dušek, Michal
Acetonyltriphenylphosphonium nitrate.
Acta Crystallographica Section E-Structure Reports Online. Roč. 69, Part 2 (2013), "o303"-"sup7". ISSN 1600-5368. E-ISSN 2056-9890
Grant - others:AV ČR(CZ) AP0701
Program: Akademická prémie - Praemium Academiae
Institutional support: RVO:68378271
Keywords : single-crystal X-ray study * T = 120 K * mean (C–C) = 0.002 A * R factor = 0.033 * wR factor = 0.094 * data-to-parameter ratio = 13.6
Subject RIV: BM - Solid Matter Physics ; Magnetism
Impact factor: 0.347, year: 2011
Crystals of the title salt, C21H20OP+.NO3-, are composed of acetonyltriphenylphosphonium cations and nitrate anions that mainly interact through electrostatic forces. The P atom in the cation has a slightly distorted tetrahedral environment, with C-P-C angles ranging from 104.79 (7) to 112.59 (6)°. The sum of O-N-O angles of the nitrate anion is 359.99°, reflecting its trigonal-planar character. C-H...O hydrogen bonds help to consolidate the crystal packing.
Permanent Link: http://hdl.handle.net/11104/0232181
Number of the records: 1