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Meta-arylation of calixarenes using organomercurial chemistry

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    0397520 - FZÚ 2014 RIV GB eng J - Journal Article
    Slavík, P. - Flídrová, K. - Dvořáková, H. - Eigner, Václav - Lhoták, P.
    Meta-arylation of calixarenes using organomercurial chemistry.
    Organic & Biomolecular Chemistry. Roč. 11, č. 33 (2013), s. 5528-5534. ISSN 1477-0520. E-ISSN 1477-0539
    Grant - others:AV ČR(CZ) AP0701
    Program: Akademická prémie - Praemium Academiae
    Institutional support: RVO:68378271
    Keywords : calix[4]arenes * mercuration * meta-substitution * supramolecular chemistry * jana2006
    Subject RIV: CC - Organic Chemistry
    Impact factor: 3.487, year: 2013

    A direct mercuration reaction combined with a subsequent Pd-catalyzed arylation was used to introduce the aryl moiety into the meta position of the calix[4]arene skeleton. The application of organomercurial intermediates thus allows the straightforward formation of meta-aryl-substituted derivatives representing a unique substitution pattern in calixarene chemistry.
    Permanent Link: http://hdl.handle.net/11104/0225133

     
     
Number of the records: 1  

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