0392271 - ÚCHP 2014 RIV DE eng J - Journal Article
Storch, Jan - Bernard, Martin - Sýkora, Jan - Karban, Jindřich - Čermák, Jan
Intramolecular Cascade Hydroarylation/Cycloisomerization Strategy for the Synthesis of Polycyclic Aromatic and Heteroaromatic Systems.
European Journal of Organic Chemistry. Roč. 2013, č. 2 (2013), s. 260-263. ISSN 1434-193X. E-ISSN 1099-0690
R&D Projects: GA ČR GAP207/10/1124; GA TA ČR TA01010646
Institutional support: RVO:67985858
Keywords : fused-ring systems * helical structures * platinum
Subject RIV: CC - Organic Chemistry
Impact factor: 3.154, year: 2013
DOI: https://doi.org/10.1002/ejoc.201201329

A new PtCl2/PtCl4-catalyzed hydroarylation/cycloisomerization cascade reaction leading to the formation of two aromatic or heteroaromatic rings in one step is reported. The strategy developed is exemplified by the synthesis of the 5,6-dihydrobenzo[c]phenanthrene and 6H-naphtho[2,1-c]chromene skeletons. Attempts to prepare [8]helicene-like molecules are also discussed.

Permanent Link: http://hdl.handle.net/11104/0221178