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Three Isomers of Aryl-Substituted Twelve-Vertex Ferratricarbollides
- 1.0391601 - ÚACH 2014 RIV US eng J - Journal Article
Bakardjiev, Mario - Štíbr, Bohumil - Holub, Josef - Grüner, Bohumír - Padělková, Z. - Růžička, A.
Three Isomers of Aryl-Substituted Twelve-Vertex Ferratricarbollides.
Organometallics. Roč. 32, č. 2 (2013), s. 377-379. ISSN 0276-7333. E-ISSN 1520-6041
R&D Projects: GA ČR(CZ) GAP207/11/0705
Institutional support: RVO:61388980
Keywords : tricarbon carborane chemistry * structural characterizations * metallatricarbaborane complexes
Subject RIV: CA - Inorganic Chemistry
Impact factor: 4.253, year: 2013
A series of the first types of monoaryl-substituted 12-vertex ferratricarbollide complexes of general constitution [1-(CpFe)-closo-ArC3B8H10] (where Ar = C6H5, 1'-C10H7, 2'-C10H7) with three different aryl substituents and arrangements of cluster carbon vertexes were isolated from high-temperature reactions between 8-Ar-nido-7,8,9-C3B8H11 compounds and [CpFe(CO)(2)](2). The Fe complexation is accompanied by extensive rearrangement of the cluster carbon atoms over the 12-vertex cage.
Permanent Link: http://hdl.handle.net/11104/0220959
Number of the records: 1