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2,2´ -[1,2-Phenylenebis(azanediyl)]diacetonitrile

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    0390221 - FZÚ 2013 RIV DK eng J - Journal Article
    Rivera, A. - Jiménez-Cruz, L. - Maldonado, M. - Kučeráková, Monika - Dušek, Michal
    2,2´ -[1,2-Phenylenebis(azanediyl)]diacetonitrile.
    Acta Crystallographica Section E-Structure Reports Online. Roč. 68, Part 12 (2012), "o429"-"sup5". ISSN 1600-5368. E-ISSN 2056-9890
    Grant - others:AV ČR(CZ) AP0701
    Program: Akademická prémie - Praemium Academiae
    Institutional research plan: CEZ:AV0Z10100521
    Keywords : single-crystal X-ray study * T = 120 K * mean sigma (C–C) = 0.002 A * R factor = 0.039 * wR factor = 0.104 * data-to-parameter ratio = 12.3
    Subject RIV: BM - Solid Matter Physics ; Magnetism
    Impact factor: 0.347, year: 2011

    The title compound, C10H10N4, shows chemical but not crystallographic C2 symmetry. The two cyanomethyl groups are located in an anti position with respect to the aromatic ring. In the crystal, molecules form parallel ladder-like tapes linked through two N—H...N hydrogen bonds. Further weak intramolecular N-H...N hydrogen bonding is responsible for the elongation of one of the Caromatic—N bonds.
    Permanent Link: http://hdl.handle.net/11104/0219088

     
     
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