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On the Stability of Fullerene C60 in Aqueous Medium

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    0381413 - ÚFCH JH 2013 RIV US eng J - Journal Article
    Gál, Miroslav - Kolivoška, Viliam - Kavan, Ladislav - Kocábová, Jana - Pospíšil, Lubomír - Hromadová, Magdaléna - Zukalová, Markéta - Sokolová, Romana - Kielar, F.
    On the Stability of Fullerene C60 in Aqueous Medium.
    Fullerenes, Nanotubes, and Carbon Nanostructures. Roč. 20, č. 8 (2012), s. 737-742. ISSN 1536-383X. E-ISSN 1536-4046
    R&D Projects: GA ČR GP203/09/P502; GA ČR GA203/09/1607; GA ČR GA203/08/1157; GA ČR GA203/09/0705; GA AV ČR IAA400400804; GA AV ČR KAN200100801
    Institutional support: RVO:61388955
    Keywords : fullerenes * AFM * dispersion
    Subject RIV: CG - Electrochemistry
    Impact factor: 0.764, year: 2012

    Fullerene C60 was dissolved in toluene-water mixture under sonochemical activation, and after toluene evaporation a stable aqueous solution remained. The problem of C60 stability in aqueous medium was studied by means of polarization modulation infrared reflection adsorption spectroscopy (PM IRRAS), time-of-flight secondary ion mass spectrometry (TOF SIMS) and atomic force microscopy/scanning tunneling microscopy (AFM/STM) techniques. It was found that C60 clusters are in the aqueous solution stabilized by the presence of thin layer of methylbenzoate produced during sonication.
    Permanent Link: http://hdl.handle.net/11104/0211889

     
     
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