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Proton affinities of 2-iminoimidazolines with bulky N-alkyl-substituents

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    0379165 - ÚOCHB 2013 RIV NL eng J - Journal Article
    Polyakova, Svetlana - Kunetskiy, Roman Alexejevič - Schröder, Detlef
    Proton affinities of 2-iminoimidazolines with bulky N-alkyl-substituents.
    International Journal of Mass Spectrometry. Roč. 314, 15 Mar (2012), s. 13-17. ISSN 1387-3806. E-ISSN 1873-2798
    Grant - others:European Research Council(XE) AdG HORIZOMS
    Institutional research plan: CEZ:AV0Z40550506
    Keywords : collision-induced dissociation * electrospray ionization * iminoimidazolines * kinetic method * proton affinity
    Subject RIV: CF - Physical ; Theoretical Chemistry
    Impact factor: 2.142, year: 2012

    The gas-phase proton affinities of 2-iminoimidazolines with bulky substituents on the ring-nitrogen atoms are investigated by the kinetic method. The experimental results are complemented by calculations using density functional theory. It turns out that the title compounds can be termed as superbases with the largest proton affinities ranging up to 260 kcal mol(-1).
    Permanent Link: http://hdl.handle.net/11104/0210427

     
     
Number of the records: 1  

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