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Cooperative interaction of protonated 1,4-diazabicyclo[2.2.2]octane with a hexaarylbenzene-based receptor: an experimental and theoretical study
- 1.0375925 - ÚMCH 2013 RIV AT eng J - Journal Article
Makrlík, E. - Toman, Petr - Vaňura, P. - Rathore, R.
Cooperative interaction of protonated 1,4-diazabicyclo[2.2.2]octane with a hexaarylbenzene-based receptor: an experimental and theoretical study.
Monatshefte fur Chemie. Roč. 143, č. 4 (2012), s. 563-568. ISSN 0026-9247. E-ISSN 1434-4475
R&D Projects: GA ČR(CZ) GAP205/10/2280
Institutional research plan: CEZ:AV0Z40500505
Keywords : receptors * macrocycles * complexation
Subject RIV: BM - Solid Matter Physics ; Magnetism
Impact factor: 1.629, year: 2012
The stability constant of a hexaarylbenzenebased receptor–protonated 1,4-diazabicyclo[2.2.2]octane complex dissolved in nitrobenzene saturated with water was determined from extraction experiments in the twophase water/nitrobenzene system and γ-activity measurements. Using quantum-mechanical calculations (DFT), the most probable structure of this complex was derived.
Permanent Link: http://hdl.handle.net/11104/0006933
Number of the records: 1