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Mesoporous titanium-manganese dioxide for sulphur mustard and soman decontamination
- 1.0370934 - ÚACH 2012 RIV GB eng J - Journal Article
Štengl, Václav - Bludská, Jana - Opluštil, F. - Němec, T.
Mesoporous titanium-manganese dioxide for sulphur mustard and soman decontamination.
Materials Research Bulletin. Roč. 46, č. 11 (2011), s. 2050-2056. ISSN 0025-5408. E-ISSN 1873-4227
R&D Projects: GA ČR GA203/08/0334
Institutional research plan: CEZ:AV0Z40320502
Keywords : oxides * chemical synthesis * X-Ray diffraction * raman spectroscopy * infrared spectroscopy
Subject RIV: CA - Inorganic Chemistry
Impact factor: 2.105, year: 2011
Titanium(IV)-manganese(IV) nano-dispersed oxides were prepared by a homogeneous hydrolysis of potassium permanganate and titanium(IV) oxo-sulphate with 2-chloroacetamide. Synthesised samples were characterised using Brunauer-Emmett-Teller (BET) surface area and Barrett-Joiner-Halenda porosity (BJH), X-ray diffraction (XRD), infrared spectroscopy (IR), and scanning electron microscopy (SEM). These oxides were taken for an experimental evaluation of their reactivity with sulphur mustard (HD or bis(2-chloroethyl)sulphide) and soman (GD or (3,3'-dimethylbutan-2-yl)-methylphosphono-fluoridate). Mn(4+) content affects the decontamination activity; with increasing Mn(4+) content the activity increases for sulphur mustard and decreases for soman. The best decontamination activities for sulphur mustard and soman were observed for samples TiMn_37 with 18.6 wt.% Mn and TiMn_5 with 2.1 wt.% Mn, respectively.
Permanent Link: http://hdl.handle.net/11104/0204606
Number of the records: 1