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Morphology and mechanical properties of polypropylene/polystyrene blends compatibilized with styrene-butadiene block copolymers

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    0370458 - ÚMCH 2012 RIV US eng J - Journal Article
    Fortelný, Ivan - Minkova, L. I. - Kotek, Jiří - Lapčíková, Monika - Michálková, Danuše
    Morphology and mechanical properties of polypropylene/polystyrene blends compatibilized with styrene-butadiene block copolymers.
    Polymer Engineering and Science. Roč. 52, č. 1 (2012), s. 191-204. ISSN 0032-3888. E-ISSN 1548-2634
    R&D Projects: GA ČR GA106/06/0729; GA AV ČR IAA200500903
    Institutional research plan: CEZ:AV0Z40500505
    Keywords : polymer blends * compatibilization * morphology
    Subject RIV: JI - Composite Materials
    Impact factor: 1.243, year: 2012

    The effect of molecular structure of styrene–butadiene block (SB) copolymers on the morphology, tensile properties, impact strength, and microhardness of polypropylene/polystyrene (PP/PS) (80/20) blends was studied. SB copolymers substantially reduce the size of dispersed PS particles formed at mixing. PS particles aggregate rapidly during compression molding and form honeycomb-like particles split by SB partitions, which persist at further annealing. Blends containing PS particles with well-developed honeycomb structure show lower yield stress, higher plasticity, and lower tensile impact strength than the blends having PS particles with simple structure.
    Permanent Link: http://hdl.handle.net/11104/0204258

     
     
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