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HCB(11)(CF(3))(n)F(11-n)(-): Inert Anions with High Anodic Oxidation Potentials
- 1.0361445 - ÚOCHB 2012 RIV US eng J - Journal Article
Fete, M. G. - Havlas, Zdeněk - Michl, Josef
HCB(11)(CF(3))(n)F(11-n)(-): Inert Anions with High Anodic Oxidation Potentials.
Journal of the American Chemical Society. Roč. 133, č. 11 (2011), s. 4123-4131. ISSN 0002-7863. E-ISSN 1520-5126
R&D Projects: GA AV ČR IAA400550708
Grant - others:NSF(US) CHE-0848477
Institutional research plan: CEZ:AV0Z40550506
Keywords : icosahedral anions * fluorinated carbaborane anions * redox potentials * gas-phase elektron detachment energy
Subject RIV: CC - Organic Chemistry
Impact factor: 9.907, year: 2011
A new type of low nucleofile anions of general formula HCB11(CF3)nF11-n were prepared. All prepared compound were electrochemically characterized and their electrochemical potentials were compared with calculations predicting gas-phase electron detachment energy of these anions.
Permanent Link: http://hdl.handle.net/11104/0198755
Number of the records: 1