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Perhaloalkylation of Metal Enolates—Unconventional and Versatile
- 1.0361368 - ÚOCHB 2012 RIV DE eng J - Journal Article
Amatov, Tynchtyk - Jahn, Ullrich
Perhaloalkylation of Metal Enolates—Unconventional and Versatile.
Angewandte Chemie - International Edition. Roč. 50, č. 20 (2011), s. 4542-4544. ISSN 1433-7851. E-ISSN 1521-3773
R&D Projects: GA ČR GA203/09/1936
Institutional research plan: CEZ:AV0Z40550506
Keywords : electron transfer * enols * perhaloalkylation * radical reactions * valence tautomerism
Subject RIV: CC - Organic Chemistry
Impact factor: 13.455, year: 2011
Radically unconventional: Natural products with di- and trichloromethyl groups and trifluoromethylated pharmaceuticals and agrochemicials are interesting compounds, often with intriguing properties. These types of compounds can be prepared by the direct perhaloalkylation of carbonyl compounds in which enolate reactivity and radical reactivity are merged.
Permanent Link: http://hdl.handle.net/11104/0198692
Number of the records: 1