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Isotope-sensitive Degenerate [1.3]-Hydrogen Migration versus Competitive Enol-Keto Tautomerization
- 1.0334353 - ÚOCHB 2010 RIV DE eng J - Journal Article
Zhang, X. - Zummack, W. - Schröder, Detlef - Weinhold, F. A. - Schwarz, H.
Isotope-sensitive Degenerate [1.3]-Hydrogen Migration versus Competitive Enol-Keto Tautomerization.
Chemistry - A European Journal. Roč. 15, č. 44 (2009), s. 11815-11819. ISSN 0947-6539. E-ISSN 1521-3765
Institutional research plan: CEZ:AV0Z40550506
Keywords : reaction mechanism * hydrogen migration * non-ergodic behavior * keto-enol tautomerism * isotope effects
Subject RIV: CF - Physical ; Theoretical Chemistry
Impact factor: 5.382, year: 2009
A careful re-investigation of the acetone cation-radical not only provides additional mechanistic insight, but reveals a degenerate 1,3-H migration as a completely novel facet.
Permanent Link: http://hdl.handle.net/11104/0179112
Number of the records: 1