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Modular synthesis of 5-substituted thiophen-2-yl C-2'-deoxyribonucleosides

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    0309166 - ÚOCHB 2009 RIV US eng J - Journal Article
    Bárta, Jan - Pohl, Radek - Klepetářová, Blanka - Ernsting, N. P. - Hocek, Michal
    Modular synthesis of 5-substituted thiophen-2-yl C-2'-deoxyribonucleosides.
    [Modulární syntéza 5-substituovaných thiofen-2-yl C-2'-deoxyribonukleosidů.]
    Journal of Organic Chemistry. Roč. 73, č. 10 (2008), s. 3798-3806. ISSN 0022-3263. E-ISSN 1520-6904
    R&D Projects: GA MŠMT LC512
    Grant - others:NIH(US) 1R03TW007372-01
    Institutional research plan: CEZ:AV0Z40550506
    Keywords : nucleosides * thiophene * cross-coupling reactions
    Subject RIV: CC - Organic Chemistry
    Impact factor: 3.952, year: 2008

    Title 5-substituted thiophen-2-yl C-2'-deoxyribonucleosides were prepared by cross-coupling reactions of bromothiophene C-nucleoside intermediates readily accessible by the Lewis acid mediated C-glycosidation of 2-bromothiophene.

    Cílové 5-substituované thiofen-2-yl C-2'-deoxyribonukleosidy byly připraveny cross-coupling reakcemi bromthiofenových C-nukleosidových intermediátů snadno dostupných C-glycosidacemi 2-bromthiofenu působením Lewisových kyselin.
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