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Improved synthesis of 1,2-.I.trans./I. ethyl 1-thioglycosides derived from 3,4,6-tri-.I.O./I.-acetyl-2-deoxy-2-phthalimido-D-hexapyranosides
- 1.0194808 - UOCHB-X 20030114 RIV CZ eng J - Journal Article
Veselý, J. - Ledvina, Miroslav - Jindřich, J. - Šaman, David - Trnka, J.
Improved synthesis of 1,2-.I.trans./I. ethyl 1-thioglycosides derived from 3,4,6-tri-.I.O./I.-acetyl-2-deoxy-2-phthalimido-D-hexapyranosides.
Collection of Czechoslovak Chemical Communications. Roč. 68, č. 7 (2003), s. 1264-1274. ISSN 0010-0765
R&D Projects: GA ČR GA203/00/0071
Institutional research plan: CEZ:AV0Z4055905
Keywords : carbohydrates * glycosides * glycoconjugates
Subject RIV: CC - Organic Chemistry
Impact factor: 1.041, year: 2003
Effective one-pot synthesis of 1,2-.I.trans./I.-acetates derived from .I.N./I.-phthaloyl-protected D-hexosamines is presented. Anomerisation of the corresponding 1,2-.I.cis./I.-acetates and direct conversion of all of them to 1,2-.I.trans./I.-ethyl 1-thioglycosides are also described and discussed.
Permanent Link: http://hdl.handle.net/11104/0090479
Number of the records: 1