0194103 - UOCHB-X 20010185 RIV FR eng J - Journal Article
Böhm, S. - Exner, Otto
Steric effects and steric inhibition of resonance: structure and ionization of 2-.I.tert./I.-butylbenzoic acid.
New Journal of Chemistry. Roč. 25, - (2001), s. 250-254. ISSN 1144-0546. E-ISSN 1369-9261
R&D Projects: GA ČR GA203/99/1454
Institutional research plan: CEZ:AV0Z4055905
Keywords : steric hindrance
Subject RIV: CC - Organic Chemistry
Impact factor: 2.440, year: 2001

Acidity of sterically hindered carboxylic acids has been explained by steric inhibition to resonance (SIR) and van der Waals tension. These two terms have evaluated comparing two isomers, 2-.I.tert./I.-butylbenzoic acid and 4-.I.tert./I.-butylbenzoic acid.
Permanent Link: http://hdl.handle.net/11104/0089794