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Excimer formation in oligo[2,5-bis(hexadecyloxy)-1,4,phenylene]s followed by fluorescence spectroscopy
- 1.0188579 - UMCH-V 20010358 RIV CZ eng J - Journal Article
Výprachtický, Drahomír - Cimrová, Věra - Machová, Luďka - Pokorná, Veronika
Excimer formation in oligo[2,5-bis(hexadecyloxy)-1,4,phenylene]s followed by fluorescence spectroscopy.
Collection of Czechoslovak Chemical Communications. Roč. 66, č. 10 (2001), s. 1473-1489. ISSN 0010-0765
R&D Projects: GA ČR GA102/98/0696; GA AV ČR KSK4050111
Institutional research plan: CEZ:AV0Z4050913
Keywords : time-resolved fluorescence spectroscopy * fluorescence lifetime * excimer
Subject RIV: CD - Macromolecular Chemistry
Impact factor: 0.778, year: 2001
With shorter oligomers (dimer, trimer), we assume a sandwich-type configuration with sufficiently close interchain distance and hence the excimer can form. Hydrophobic interactions of long aliphatic side chains in a polar medium play an important role in the excimer formation.
Permanent Link: http://hdl.handle.net/11104/0084491
Number of the records: 1