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Electrocapillary Activity and Adsorptive Accumulation of U(VI)-Cupferron and U(VI)-Chloranilic Acid Complexes on Mercury Electrode

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    0181768 - UFCH-W 20030207 RIV DE eng J - Journal Article
    Novotný, Ladislav - Navrátil, Tomáš - Sander, S. - Bašová, P.
    Electrocapillary Activity and Adsorptive Accumulation of U(VI)-Cupferron and U(VI)-Chloranilic Acid Complexes on Mercury Electrode.
    Electroanalysis. Roč. 15, č. 21 (2003), s. 1687-1692. ISSN 1040-0397. E-ISSN 1521-4109
    R&D Projects: GA ČR GA203/98/P239
    Institutional research plan: CEZ:AV0Z4040901
    Keywords : interfacial activity * uranium-complexes * cupferron
    Subject RIV: CG - Electrochemistry
    Impact factor: 1.811, year: 2003

    Interfacial activity of uranium(VI) - cupferron and uranium(VI) -chloranilic acid(CAA) complexes on polarized mercury electrode at 110mV, 10mV or - 240mV respectively vs.saturated calomel electrode (SCE), and under conditions of the application of adsorptive stripping voltammetric techniques was studied. It relevaed a competitive effect of interfacial activity of the mentioned complexes consisting in a nonmonotonous effect of the bulk concentration of U(VI) on the adsorption of the mentioned complexing reagents at their constant concentrations.
    Permanent Link: http://hdl.handle.net/11104/0078289

     
     

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