0181564 - UFCH-W 20020201 RIV US eng M - Monography Chapter
Ludvík, Jiří - Cibulka, R.
Electroreduction of Methyl Azinyl Ketoximes and Their Ni(II), Cu(II), and Zn(II) Complexes on Mercury - Correlation with Their Hydrolytic Activity.
Organic Electrochemistry. Pennington: ECS, 2002 - (Baizer, M.), s. 142-146. ECS., AE1
R&D Projects: GA ČR GA203/01/1093
Keywords : ketoximes * chelates * electroreduction
Subject RIV: CF - Physical ; Theoretical Chemistry

Ketoximes and their metal chelate complexes are both active as catalysts in hydrolysis of esters. Electroreduction of five azinylmethylketoximes I-V and their Ni(II), Cu(II) and Zn(II) complexes was investigated polarographically and correlated with acidity of hydroxyimino group, nucleophilicity of dissociated oximate anion and with hydrolytic activity towards model substrate (p-nitrophenylacetate). Three different types of reduction of chelates were observed and their influence on the catalytic activity discussed.
Permanent Link: http://hdl.handle.net/11104/0078114