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Aluminium Distribution in MCM-22. The Effect of Framework Aluminium Content and Synthesis Procedure

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    0181468 - UFCH-W 20020136 RIV NL eng C - Conference Paper (international conference)
    Dědeček, Jiří - Čejka, Jiří - Oberlinger, M. - Ernst, S.
    Aluminium Distribution in MCM-22. The Effect of Framework Aluminium Content and Synthesis Procedure.
    Impact of Zeolites and Other Porous Materials on the New Technologies at the Beginning of the New Millennium. Amsterdam: Elsevier, 2002 - (Aiello, R.; Giordano, G.; Testa, F.), s. 23-30. Studies in Surface Science and Catalysis., 142 A.
    [International FEZA Conference /2./. Taormina (IT), 01.09.2002-05.09.2002]
    R&D Projects: GA AV ČR IAA4040001
    Institutional research plan: CEZ:AV0Z4040901
    Keywords : aluminium * MCM-22 * Co(II)
    Subject RIV: CF - Physical ; Theoretical Chemistry

    The distribution of single aluminium atoms and aluminium pairs in the framework of zeolite MCM-22 was investigated using sodium and Co(II) ion-exchange and UV-Vis spectroscopy of Co(II) ions located in cationic positions at maximum Co loading in MCM-22 zeolite. Aluminium distribution between individual Al types in the MCM-22 structure depends on the framework aluminium content and conditions of zeolite synthesis.
    Permanent Link: http://hdl.handle.net/11104/0078032

     
     

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