0181441 - UFCH-W 20020107 RIV NL eng M - Monography Chapter
Balcar, Hynek - Sedláček, J. - Zednik, J. - Vohlídal, J. - Blechta, Vratislav
Polymerisation of Unconventional Monosubstituted Acetylenes with Metathesis and Insertion Catalysts.
1-4020-0559-8. In: Ring Opening Metathesis Polymerization and Related Chemistry. State of the Art and Visions for the New Century. Dordrecht: Kluwer Academic, 2002 - (Khosravi, E.; Szymanska-Buzar, T.), s. 417-424. NATO Science Series. Mathematics, Physics, and Chemistry.
R&D Projects: GA ČR GA203/98/1165
Institutional research plan: CEZ:AV0Z4040901
Keywords : acetylene polymerization * metathesis * polyacetylenes
Subject RIV: CF - Physical ; Theoretical Chemistry

Critical survey of transition metal catalysts for polymerization of monosubstituted acetylenes. The applicability of W- and Mo-based metathesis as well as Rh- and Pd-based insertion catalysts is given with respect to (i) catalyst tolerance of heteroatom-containing substitutents in monomer and (ii) properties of produced polymers (molecular weight characteristics, microstructure, spectroscopic properties.
Permanent Link: http://hdl.handle.net/11104/0078011