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Nanomorphology of Polymer Frameworks and Their Role as Templates for Generating Size-Controlled Metal Nanoclusters
- 1.0166932 - UCHP-M 20030250 RIV DE eng J - Journal Article
Artuso, F. - D'Archivio, A. A. - Lora, S. - Jeřábek, Karel - Králik, E. - Corain, B.
Nanomorphology of Polymer Frameworks and Their Role as Templates for Generating Size-Controlled Metal Nanoclusters.
Chemistry - A European Journal. Roč. 9, č. 21 (2003), s. 5292-5296. ISSN 0947-6539. E-ISSN 1521-3765
Grant - others:GA-(IT) 2001038991; VEGA(SK) 1/9142/02
Institutional research plan: CEZ:AV0Z4072921
Keywords : nanoclusters * nano-structures * gel-type resins
Subject RIV: CI - Industrial Chemistry, Chemical Engineering
Impact factor: 4.353, year: 2003
The obtained composite MPIF-Na+/Pd-0 is prepared upon reducing, in ethanol, MPIF-Pd0.52+, obtained upon previous homogeneous dispersion of "Pd2+" inside the resin particles (XRMA control) through ion-exchange. Metal nanoclusters appear to be size-controlled (2.0 +/- 0.2 nm) and are seen to reasonably fit the predominant resin "nanopores" diameter, determined in ethanol (3.2 nm) by means of inverse steric exclusion chromatography (ISEC).
Permanent Link: http://hdl.handle.net/11104/0064040
Number of the records: 1