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The Synthesis of Rhodium Complexes with Cyclopentadienyl Ligands Containing Perfluoroalkyl Ponytails
- 1.0166276 - UCHP-M 20013213 IT eng C - Conference Paper (international conference)
Auerová, Kateřina - Čermák, Jan - Nguyen, Huong Thi Thu - Blechta, Vratislav
The Synthesis of Rhodium Complexes with Cyclopentadienyl Ligands Containing Perfluoroalkyl Ponytails.
Abstracts. 2001, s. 39-40.
[International School of Organometallic Chemistry /3./. Camerino (IT), 09.09.2001-13.09.2001]
R&D Projects: GA ČR GA203/99/0135
Institutional research plan: CEZ:AV0Z4072921
Keywords : synthesis of complexes * model compounds
Subject RIV: CC - Organic Chemistry
The synthesis of complexes, which can be used as model compounds for catalysis in fluorous biphase systems, is reported. Modified cyclopentadienes of general formula C5Me4H(CnF2n+1) (n = 3,5,7,9), and their complexes with rhodium in two oxidation states: [RhCl2(C5Me4(CnF2n+1))]2 and Rh(CO)2(C5Me4(CnF2n+1)) were prepared. The electronic properties of the ligands and partition coefficients of all compounds synthesised in the system perfluor(methylcyclohexane)-toluene are reported, as well as the structures of isomers of the ligand precursors and the crystal structure of complex [RhCl2(C5Me4(C8F17))]2.
Permanent Link: http://hdl.handle.net/11104/0063404
Number of the records: 1