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On Molecular-Based Equations of State: Rigor versus Speculations
- 1.0166206 - UCHP-M 20013062 RIV NL eng J - Journal Article
Nezbeda, Ivo
On Molecular-Based Equations of State: Rigor versus Speculations.
Fluid Phase Equilibria. Roč. 182, - (2001), s. 3-15. ISSN 0378-3812. E-ISSN 1879-0224
R&D Projects: GA ČR GA203/99/0134; GA AV ČR IAA4072712
Institutional research plan: CEZ:AV0Z4072921
Subject RIV: CF - Physical ; Theoretical Chemistry
Impact factor: 1.217, year: 2001
A general scheme for developing any semi-empirical molecular-based equation of state is formulated along with several rules which reflect the essentials of physics of fluids and which should be observed. Approximations and simplifications used in the implementation of the scheme are analyzed in the light of these rules and examples showing superiority of molecular-based considerations over purely intuitive or empirical ones are presented.
Permanent Link: http://hdl.handle.net/11104/0063346
Number of the records: 1