Amino-substituted ferra-bis(tricarbollides) - Metallatricarbaboranes designed for linear molecular constructions

0100757 - UACH-T 20043004 RIV DE eng J - Journal Article
Grüner, Bohumír - Bačkovský, Jaroslav - Sillanpää, R. - Kivekäs, R. - Císařová, I. - Teixidor, F. - Viñas, C. - Štíbr, Bohumil
Amino-substituted ferra-bis(tricarbollides) - Metallatricarbaboranes designed for linear molecular constructions.
[Amino-substituované ferra-bis(trikarbaborany)-matallatrikarbaborany navržené pro lineární molekulární konstrukce.]
European Journal of Inorganic Chemistry. -, č. 7 (2004), s. 1402-1410. ISSN 1434-1948. E-ISSN 1099-0682
R&D Projects: GA ČR GA203/00/1042; GA MŠMT LN00A028
Institutional research plan: CEZ:AV0Z4032918
Keywords : boranes * carboranes * metallacarboranes
Subject RIV: CA - Inorganic Chemistry
Impact factor: 2.336, year: 2004

Reactions between high purity FeCl2 and the anion [nido-7-(tBuHN)-7,8,9-C3B8H10)](-) (1(-)) have been used for efficient syntheses of the twelve-vertex double-cluster metallatricarbollide complexes of the para,para (p,p) type [closo-9,9'-(RHN)(2)-commo-2,2'-Fe-II-1,7,9-(C3B8H10)-1',7',9'-(C3B8H10)] (2) (2a, R = tBu and 2b, R = H) (yields 42-45

Amino-substituované ferra-bis(trikarbaborany)-matallatrikarbaborany navržené pro lineární molekulární konstrukce.
Permanent Link: http://hdl.handle.net/11104/0008248