Use of emanation thermal analysis to characterize thermal reactivity of brannerite mineral

0097337 - ÚACH 2008 RIV HU eng J - Journal Article
Balek, V. - Vance, E.R. - Zeleňák, V. - Málek, Z. - Šubrt, Jan
Use of emanation thermal analysis to characterize thermal reactivity of brannerite mineral.
[Použití emanační termické analýzy pro charakterizaci reaktivity minerálu branneritu za zvýšené teploty.]
Journal of Thermal Analysis and Calorimetry. Roč. 88, č. 1 (2007), s. 93-98. ISSN 1388-6150. E-ISSN 1588-2926
Grant - others:GA MŠk(CZ) LA 292; GA MŠk(CZ) ME 879
Institutional research plan: CEZ:AV0Z40320502
Keywords : brannerite * emanation thermal analysis
Subject RIV: CA - Inorganic Chemistry
Impact factor: 1.483, year: 2007

Emanation thermal analysis (ETA) was used to characterize the thermal reactivity of amorphous brannerite mineral of general formula U1-xTi2+xO6 (locality El Cabril, near Cordoba, Spain). It was demonstrated that on sample heating up to 880 degrees C microstructure changes taking place in the sample were accompanied by the formation of new radon diffusion paths, followed by their closing up during the final transformation of amorphous to crystalline brannerite in the range 900-1020 degrees C. Relative changes in structure irregularities that served as radon diffusion paths during heating and subsequent cooling of the sample to temperatures of 300, 550, 750, 880, 1020 and 1130 degrees C, respectively, were determined from the ETA results. Mass losses in temperature ranges of 230-315, 570-760 and 840-1040 degrees C were observed by thermogravimetry. Mass spectrometry indicated the release of CO2 mainly due to the decomposition of minor carbon amount in the brannerite mineral sample.

Metoda emanační termické analýzy (ETA) byla použita pro charakterizaci změn při zahřívání minerálu branneritu, amorfního oxidu U1-xTi2+xO6, z lokality El Cabril ve Španělsku.
Permanent Link: http://hdl.handle.net/11104/0156502