Morphology of polystyrene-block-poly(styrene-co-acrylonitrile) and polystyrene-block-poly(styrene-co-acrylonitrile-co-5-vinyltetrazole) diblock copolymers prepared by nitroxide-mediated radical polymerization and „click“ chemistry

0094958 - ÚMCH 2008 RIV GB eng J - Journal Article
Gromadzki, Daniel - Lokaj, Jan - Černoch, Peter - Diat, O. - Nallet, F. - Štěpánek, Petr
Morphology of polystyrene-block-poly(styrene-co-acrylonitrile) and polystyrene-block-poly(styrene-co-acrylonitrile-co-5-vinyltetrazole) diblock copolymers prepared by nitroxide-mediated radical polymerization and „click“ chemistry.
[Morfologie diblokových kopolymerů polystyren-blok-poly(styren-co-akrylonitril) a polystyren-blok-poly(styren-co-akrylonitril-co-5-vinyltetrazol) připravených nitroxidovou metodou radikálové polymerizace a chemického procesu "kliknutí".]
European Polymer Journal. Roč. 44, č. 1 (2008), s. 189-199. ISSN 0014-3057. E-ISSN 1873-1945
R&D Projects: GA ČR GESON/06/E005
Grant - others:Marie Curie Fellowship(EU) HPMT-CT-2001-00396
Institutional research plan: CEZ:AV0Z40500505
Keywords : polystyrene-block-poly(styrene-co-acrylonitrile-co-5-vinyltetrazole) * TEMPO * click chemistry
Subject RIV: CD - Macromolecular Chemistry
Impact factor: 2.143, year: 2008

Well-defined polystyrene-block-poly(styrene-co-acrylonitrile) PS-block-P(S-co-AN) and poly(styrene-co-acrylonitrile-co-5-vinyltetrazole) PS-block-P(S-co-AN-co-5VT) block copolymers with various content of acrylonitrile units in the statistical block were synthesized by nitroxide mediated radical polymerization (NMRP) and post-functionalized using efficient click chemistry process. Their morphology was studied.

Blokové kopolymery polystyren-blok-poly(styren-co-akrylonitril) a polystyren-blok-poly(styren-co-akrylonitril-co-5-vinyltetrazol) s definovanou strukturou a s různým obsahem akrylonitrilových jednotek ve statistickém bloku byly syntetizovány nitroxidovou metodou radikálové polymerizace (NMRP) a následně funkcionalizovány účinným chemickým procesem kliknutí. Byla studována jejich morfologie.
Permanent Link: http://hdl.handle.net/11104/0004401