Macropolyhedral boron-containing cluster chemistry. The unique nido-five-vertex- B-2 -nido-ten-vertex conjuncto structure of [(eta(5)-C5Me5)(2)Rh2B11H15] via an unexpected cluster-dismantling

0094288 - ÚACH 2008 RIV GB eng J - Journal Article
Carr, MJ. - Perera, SD. - Jelínek, Tomáš - Štíbr, Bohumil - Clegg, W. - Kilner, C. A. - Kennedy, D. J.
Macropolyhedral boron-containing cluster chemistry. The unique nido-five-vertex- B-2 -nido-ten-vertex conjuncto structure of [(eta(5)-C5Me5)(2)Rh2B11H15] via an unexpected cluster-dismantling.
[Makropolyedrická klastrová chemie boru. Unikátní nido-5-vrcholová-B2-nido-10-vrcholová conjucto struktura [(eta5-C5Me5)2RhB11H15] vzniklá neočekávanou demontáží klastru.]
Chemical Communications. Roč. 34, - (2007), s. 3559-3561. ISSN 1359-7345. E-ISSN 1364-548X
R&D Projects: GA ČR GA203/05/2646; GA AV ČR(CZ) IAA400320601
Grant - others:EPSRC(GB) J/56929; EPSRC(GB) GR/L/49505; EPSRC(GB) R/61949
Institutional research plan: CEZ:AV0Z40320502
Keywords : nuclear magnetic resonance
Subject RIV: CA - Inorganic Chemistry
Impact factor: 5.141, year: 2007

B16H20 and [RhCl2(eta(5)-C5Me5)](2) with tmnd give [(eta(5)-C5Me5)(2)Rh2B11H15], which has an unprecedented thirteenvertex macropolyhedral cluster core based on a nido ten-vertex {MB9} subcluster and a nido five-vertex {MB4} subcluster fused with their open-face {B-2} edges in common.

Makropolyhedrická klastrová chemie boru. Unikátní nido-5-vrcholová-B2-nido-10-vrcholová conjucto struktura [(eta(5)-C5Me5)2RhB11H15] vzniklá neočekávanou demontáží klastru.
Permanent Link: http://hdl.handle.net/11104/0154128