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Chiral superbases: The proton affinities of 1- and 2-aza[6]helicene in the gas phase

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    0089465 - ÚOCHB 2008 RIV GB eng J - Journal Article
    Roithová, Jana - Schröder, Detlef - Míšek, Jiří - Stará, Irena G. - Starý, Ivo
    Chiral superbases: The proton affinities of 1- and 2-aza[6]helicene in the gas phase.
    [Chirální superbáze: protonové afinity 1- and 2-aza[6]helicenů v plynné fázi.]
    Journal of Mass Spectrometry. Roč. 42, č. 9 (2007), s. 1233-1237. ISSN 1076-5174. E-ISSN 1096-9888
    R&D Projects: GA AV ČR KJB4040302; GA AV ČR KJB400550704
    Grant - others:Framework Programme(XE) LSHC-CT-2006-015847
    Institutional research plan: CEZ:AV0Z40550506
    Source of funding: R - Framework programmes of European Commission
    Keywords : azahelicenes * density functional theory * kinetic method * proton affinity
    Subject RIV: CF - Physical ; Theoretical Chemistry
    Impact factor: 3.062, year: 2007

    The proton affinities of 1- and 2-azahelicene are determined using experimental and theoretical methods. With PAs of about 1000 kJ mol-1, the helical backbone of both compounds offer promising perspectives for future research on enantioselective reactions.

    Protonové afinity 1- a 2-azahelicenů jsou určeny experimentálními a teoretickými metodami. Protonové afinity jsou okolo 1000 kJ.mol-1, helikální kostra těchto sloučenin dává příslib do budoucna při výzkumu enantioselektivních reakcí.
    Permanent Link: http://hdl.handle.net/11104/0150671

     
     
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