0615014 - FZÚ DATA Scientific data - ASEP      2025
Otta, Jaroslav - Mikuláštík, J. - Šípka, R. - Stein, M. - Kühne, Irina A. - Vrňata, M. - Vlček, Jan

Dataset-PILs-Sensors ACS-Omega.

Description: Abstract: we investigate the interactions between five representative gaseous analytes and two poly(ionic liquid)s (PILs) based on the sulfopropylacrylate polyanion in combination with the alkylphosphonium cations, P4,4,4,4 and P4,4,4,8, and their nanocomposites with fullerenes (C60, C70) to reveal the potential of PILs as sensitive layers for gas sensors. The gaseous analytes were chosen based on their molecular size (all of them containing two carbon atoms) and variation of functional groups: alcohol (ethanol), nitrile (acetonitrile), aldehyde (acetaldehyde), halogenated alkane (bromoethane) and carboxylic acid (acetic acid). The six variations of PILs - P4,4,4,4SPA (1), P4,4,4,4SPA+C60 (1+C60), P4,4,4,4SPA+C70 (1+C70), and P4,4,4,8SPA (2), P4,4,4,8SPA+C60 (2+C60), P4,4,4,8SPA+C70 (2+C70) - were characterized by UV-Vis and Raman spectroscopy, and their interactions with each gaseous analyte were studied using electrochemical impedance spectroscopy. Exposure of all PIL samples to acetaldehyde, bromoethane and ethanol leads to a decrease in the diffusion coefficient, while exposure to acetic acid reveals an increase. Fullerene-doping significantly enhances the response to the analyte. Semi-empirical quantum mechanical xTB-GFN2 calculations revealed that hydrogen bonding and proton transfer events play an important role during the detection process.

Data: Figures (as png, jpg or tif files), tables (as csv files)
Readme.txt (Title, Authors, Affiliations, Abstract, DOI, data description)
Keywords : polymer ionic liquids * gas sensors * fullerene
R&D Projects: GA MŠMT(CZ) EH22_008/0004596; GA ČR(CZ) GA23-05878S; GA MŠMT(CZ) EF16_019/0000760
Institutional support: RVO:68378271
OECD category: Physical chemistry
DOI: https://doi.org/10.57680/asep.0615014
Handle: https://hdl.handle.net/11104/0363450
Depositor: admin
Date of release: 7.2.2025
 
Publicat.:
Fullerene-doped poly(ionic liquids) as small molecular gas sensors─control of intermolecular interactions

0380790 - ÚFA 2013 RIV US eng C - Konferenční příspěvek (zahraniční konf.)
Pickett, J. S. - Christopher, I. W. - Grison, Benjamin - Grimald, S. - Santolík, Ondřej - Décréau, P. M. E. - Lefebvre, B. - Engebretson, M. J. - Kistler, L. M. - Constantinescu, D. - Chen, L. J. - Omura, Y. - Lakhina, G. S. - Gurnett, D. A. - Cornilleau-Wehrlin, N. - Fazakerley, A. N. - Dandouras, I. - Lucek, E.
On The Propagation And Modulation Of Electrostatic Solitary Waves Observed Near The Magnetopause On Cluster.
AIP Conference Proceedings. Vol. 1320. Melville: American Institute of Physics, 2010 - (Vassiliadis, D.; Fung, S.; Daglis, I.; Huba, J.), s. 115-124. ISBN 978-0-7354-0875-3. ISSN 0094-243X.
[Conference on Modern Challenges in Nonlinear Plasma Physics. Chalkidiki (GR), 15.06.2009-19.06.2009]
Výzkumný záměr: CEZ:AV0Z30420517
Klíčová slova: Magnetopause * Electrostatic Solitary Waves * Pc1 Waves * Buneman Instability
Kód oboru RIV: BL - Fyzika plazmatu a výboje v plynech
Web výsledku:
http://dx.doi.org/10.1063/1.3544316DOI: https://doi.org/10.1063/1.3544316
Trvalý link: http://hdl.handle.net/11104/0211410

0308661 - ÚTIA 2008 RIV NL eng J - Článek v odborném periodiku
Ioffe, A. D. - Outrata, Jiří
On metric and calmness qualification conditions in subdifferential calculus.
[Kvalifikační podmínky subdiferenciálního počtu založené na metrických a klidnostních odhadech.]
Set-Valued Analysis. Roč. 16, 2/3 (2008), s. 199-227. ISSN 0927-6947
Grant CEP: GA AV ČR IAA1075402
Výzkumný záměr: CEZ:AV0Z10750506
Klíčová slova: subdifferential calculus * qualification conditions * metric estimates * calmness
Kód oboru RIV: BA - Obecná matematika
Impakt faktor: 0.714, rok: 2008 ; AIS: 0.869, rok: 2008
DOI: https://doi.org/10.1007/s11228-008-0076-x
Trvalý link: http://hdl.handle.net/11104/0161071

0496994 - ÚCHP 2019 IT eng C - Konferenční příspěvek (zahraniční konf.)
Váňa, Lubomír - Storch, Jan - Církva, Vladimír
Synthesis and Funcionalization of Phenacenes and Helicenes containing δ-Lactam Ring.
Abstract Book. -: -, 2018, č. článku P467. ISBN N.
[International Conference on Organic Synthesis 22-ICOS /22./. Florence (IT), 16.09.2018-21.09.2018]
Grant CEP: GA MPO FV10082; GA ČR(CZ) GA17-02578S
Institucionální podpora: RVO:67985858
Klíčová slova: helicene * fenacene * synthesis
Obor OECD: Organic chemistry
Trvalý link: http://hdl.handle.net/11104/0289606