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Surface roughness improvement of near net shaped alumina by EPD

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Abstract

The high surface roughness of thick and dense alumina deposits prepared by long-term electrophoretic deposition (EPD) caused by surface inhomogeneities could be eliminated by changing the suspension composition or EPD parameters. This work is aimed at the influence of the suspension composition, more precisely on the increase of electrical conductivity through indifferent electrolyte (lithium chloride) addition and its effect on the surface roughness. At first, the electrical conductivity was adjusted by the various amounts of the stabilisers of mono-, di- and trichloroacetic acid in the range of 0.85–21.25 wt%. It was demonstrated that deposits prepared from these suspensions were several millimetres thick, dense with a relatively low surface roughness (Ra ≈ 10 μm) only when the electrical conductivity was higher than 4 μS/cm. If a portion of the stabiliser was replaced with indifferent electrolyte, it resulted in the significantly smoother surface with a roughness Ra ≈ 2 μm preserving all other benefits. Suggested optimization represents a useful novel approach for the preparation of dense, thick and near net-shaped alumina deposits with low surface roughness via EPD.

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References

  1. Sarkar, P., Nicholson, P.S.: Electrophoretic deposition (EPD): mechanisms, kinetics, and application to ceramics. J. Am. Ceram. Soc. 79(8), 1987–2002 (1996). https://doi.org/10.1111/j.1151-2916.1996.tb08929.x

    Article  CAS  Google Scholar 

  2. Besra, L., Uchikoshi, T., Suzuki, T.S., Sakka, Y.: Application of constant current pulse to suppress bubble incorporation and control deposit morphology during aqueous electrophoretic deposition (EPD). J. Eur. Ceram. Soc. 29(10), 1837–1845 (2009). https://doi.org/10.1016/j.jeurceramsoc.2008.07.031

    Article  CAS  Google Scholar 

  3. Tahmasbi Rad, A., Solati-Hashjin, M., Osman, N.A.A., Faghihi, S.: Improved bio-physical performance of hydroxyapatite coatings obtained by electrophoretic deposition at dynamic voltage. Ceram. Int. 40(8, Part B), 12681–12691 (2014). https://doi.org/10.1016/j.ceramint.2014.04.116

    Article  CAS  Google Scholar 

  4. Besra, L., Liu, M.: A review on fundamentals and applications of electrophoretic deposition (EPD). Prog. Mater. Sci. 52(1), 1–61 (2007). https://doi.org/10.1016/j.pmatsci.2006.07.001

    Article  CAS  Google Scholar 

  5. Diba, M., Fam, D.W.H., Boccaccini, A.R., Shaffer, M.S.P.: Electrophoretic deposition of graphene-related materials: a review of the fundamentals. Prog. Mater. Sci. 82, 83–117 (2016). https://doi.org/10.1016/j.pmatsci.2016.03.002

    Article  CAS  Google Scholar 

  6. Ferrari, B., Moreno, R.: Electrophoretic deposition of aqueous alumina slips. J. Eur. Ceram. Soc. 17(4), 549–556 (1997). https://doi.org/10.1016/S0955-2219(96)00113-6

    Article  CAS  Google Scholar 

  7. Milani, M., Zahraee, S.M., Mirkazemi, S.M.: Influence of electrophoretic deposition parameters on pore size distribution of doped nano alumina plates. Ceramics-Silikáty. 60(4), 299–307 (2016). https://doi.org/10.13168/cs.2016.0045

    Article  CAS  Google Scholar 

  8. Hasanpoor, M., Aliofkhazraei, M., Delavari, H.,.H.: In-situ study of mass and current density for electrophoretic deposition of zinc oxide nanoparticles. Ceram. Int. 42(6), 6906–6913 (2016). https://doi.org/10.1016/j.ceramint.2016.01.076

  9. Javidi, M., Javadpour, S., Bahrololoom, M.E., Ma, J.: Electrophoretic deposition of natural hydroxyapatite on medical grade 316L stainless steel. Mater. Sci. Eng. C. 28(8), 1509–1515 (2008). https://doi.org/10.1016/j.msec.2008.04.003

    Article  CAS  Google Scholar 

  10. Meng, X., Kwon, T.Y., Yang, Y., Ong Joo, L., Kim, K.H.: Effects of applied voltages on hydroxyapatite coating of titanium by electrophoretic deposition. J Biomed Mater Res B Appl Biomater. 78B(2), 373–377 (2006). https://doi.org/10.1002/jbm.b.30497

    Article  CAS  Google Scholar 

  11. Hadraba, H., Chlup, Z., Drdlik, D., Cihlar, J.: Micro-fibres containing composites prepared by EPD. J. Eur. Ceram. Soc. 36(2), 365–371 (2016). https://doi.org/10.1016/j.jeurceramsoc.2015.07.031

    Article  CAS  Google Scholar 

  12. Maca, K., Pouchly, V., Drdlik, D., Hadraba, H., Chlup, Z.: Dilatometric study of anisotropic sintering of alumina/zirconia laminates with controlled fracture behaviour. J. Eur. Ceram. Soc. 37(14), 4287–4295 (2017). https://doi.org/10.1016/j.jeurceramsoc.2017.04.030

    Article  CAS  Google Scholar 

  13. Hung, C.-W., Chang, C.-H., Chen, W.-C., Chen, C.-C., Chen, H.-I., Tsai, Y.-T., Tsai, J.-H., Liu, W.-C.: A Pt/AlGaN/GaN heterostructure field-effect transistor (HFET) prepared by an electrophoretic deposition (EPD)-gate approach. Solid State Electron. 124, 5–9 (2016). https://doi.org/10.1016/j.sse.2016.06.011

    Article  CAS  Google Scholar 

  14. Keller, F., Nirschl, H., Dörfler, W., Woldt, E.: Efficient numerical simulation and optimization in electrophoretic deposition processes. J. Eur. Ceram. Soc. 35(9), 2619–2630 (2015). https://doi.org/10.1016/j.jeurceramsoc.2015.02.031

    Article  CAS  Google Scholar 

  15. Michaud, X., Shi, K., Zhitomirsky, I.: Electrophoretic deposition of LiFePO4 for Li-ion batteries. Mater. Lett. 241, 10–13 (2019). https://doi.org/10.1016/j.matlet.2019.01.032

    Article  CAS  Google Scholar 

  16. Esfahani, S.L., Rouhani, S., Ranjbar, Z.: Optimization the electrophoretic deposition fabrication of graphene-based electrode to consider electro-optical applications. Surf. Interfaces. 9, 218–227 (2017). https://doi.org/10.1016/j.surfin.2017.10.001

    Article  CAS  Google Scholar 

  17. Song, G., Xu, G., Quan, Y., Yuan, Q., Davies, P.A.: Uniform design for the optimization of Al2O3 nanofilms produced by electrophoretic deposition. Surf. Coat. Technol. 286, 268–278 (2016). https://doi.org/10.1016/j.surfcoat.2015.12.039

    Article  CAS  Google Scholar 

  18. Drdlik, D., Moravek, T., Rahel, J., Stupavska, M., Cihlar, J., Drdlikova, K., Maca, K.: Electrophoretic deposition of plasma activated sub-micron alumina powder. Ceram. Int. 44(8), 9787–9793 (2018). https://doi.org/10.1016/j.ceramint.2018.02.215

    Article  CAS  Google Scholar 

  19. Ervina, J., Ghaleb, Z.A., Hamdan, S., Mariatti, M.: Colloidal stability of water-based carbon nanotube suspensions in electrophoretic deposition process: effect of applied voltage and deposition time. Compos. A: Appl. Sci. Manuf. 117, 1–10 (2019). https://doi.org/10.1016/j.compositesa.2018.11.002

    Article  CAS  Google Scholar 

  20. Ferrari, B., Moreno, R.: The conductivity of aqueous Al2O3 slips for electrophoretic deposition. Mater. Lett. 28(4), 353–355 (1996). https://doi.org/10.1016/0167-577X(96)00075-4

    Article  CAS  Google Scholar 

  21. Lefrou, C., Fabry, P., Poignet, J.C.: Electrochemistry: the Basics, with Examples. Springer, Berlin Heidelberg (2012)

    Book  Google Scholar 

  22. Cruz, R.C.D., Reinshagen, J., Oberacker, R., Segadães, A.M., Hoffmann, M.J.: Electrical conductivity and stability of concentrated aqueous alumina suspensions. J. Colloid Interface Sci. 286(2), 579–588 (2005). https://doi.org/10.1016/j.jcis.2005.02.025

    Article  CAS  Google Scholar 

  23. Liu, X., Maki-Arvela, P., Aho, A., Vajglova, Z., Gun’ko, V.M., Heinmaa, I., Kumar, N., Eranen, K., Salmi, T., Murzin, D.Y.: Zeta potential of beta zeolites: influence of structure, acidity, pH, temperature and concentration. Molecules (Basel, Switzerland). 23(4), (2018). https://doi.org/10.3390/molecules23040946

  24. Krüger, H.G., Knote, A., Schindler, U., Kern, H., Boccaccini, A.R.: Composite ceramic-metal coatings by means of combined electrophoretic deposition and galvanic methods. J. Mater. Sci. 39(3), 839–844 (2004). https://doi.org/10.1023/B:JMSC.0000012912.96350.d2

    Article  Google Scholar 

  25. Cihlar, J., Drdlik, D., Cihlarova, Z., Hadraba, H.: Effect of acids and bases on electrophoretic deposition of alumina and zirconia particles in 2-propanol. J. Eur. Ceram. Soc. 33(10), 1885–1892 (2013). https://doi.org/10.1016/j.jeurceramsoc.2013.02.017

    Article  CAS  Google Scholar 

  26. Safarík, L., Stránský, Z.: Titrimetric Analysis in Organic Solvents. Elsevier, Amsterdam (1986)

    Google Scholar 

  27. Izutsu, K.: Electrochemistry in Nonaqueous Solutions. Wiley, (2009)

  28. Ji, C., Lan, W., Xiao, P.: Fabrication of yttria-stabilized zirconia coatings using electrophoretic deposition: packing mechanism during deposition. J. Am. Ceram. Soc. 91(4), 1102–1109 (2008). https://doi.org/10.1111/j.1551-2916.2008.02261.x

    Article  CAS  Google Scholar 

  29. Guo, F., Shapiro, I.P., Xiao, P.: Effect of HCl on electrophoretic deposition of yttria stabilized zirconia particles in organic solvents. J. Eur. Ceram. Soc. 31(14), 2505–2511 (2011). https://doi.org/10.1016/j.jeurceramsoc.2011.02.027

    Article  CAS  Google Scholar 

  30. Anné, G., Vanmeensel, K., Neirinck, B., Van der Biest, O., Vleugels, J.: Ketone-amine based suspensions for electrophoretic deposition of Al2O3 and ZrO2. J. Eur. Ceram. Soc. 26(16), 3531–3537 (2006). https://doi.org/10.1016/j.jeurceramsoc.2006.01.019

    Article  CAS  Google Scholar 

  31. Hirata, Y., Nishimoto, A., Ishihara, Y.: Forming of alumina powder by electrophoretic deposition. J. Ceram. Soc. Jpn. International ed. 99(2), 105–109 (1991)

    Google Scholar 

  32. Kreethawate, L., Larpkiattaworn, S., Jiemsirilers, S., Besra, L., Uchikoshi, T.: Application of electrophoretic deposition for inner surface coating of porous ceramic tubes. Surf. Coat. Technol. 205(7), 1922–1928 (2010). https://doi.org/10.1016/j.surfcoat.2010.08.069

    Article  CAS  Google Scholar 

  33. Basu, R.N., Randall, C.A., Mayo, M.J.: Fabrication of dense zirconia electrolyte films for tubular solid oxide fuel cells by electrophoretic deposition. J. Am. Ceram. Soc. 84(1), 33–40 (2001). https://doi.org/10.1111/j.1151-2916.2001.tb00604.x

    Article  CAS  Google Scholar 

  34. Hamaker, H.C., Verwey, E.J.W.: The role of the forces between the particles in electrodeposition and other phenomena. Trans. Faraday Soc. 36, 180–185 (1940)

    Article  CAS  Google Scholar 

  35. Zhitomirsky, I., Gal-Or, L.: Electrophoretic deposition of hydroxyapatite. J. Mater. Sci. Mater. Med. 8(4), 213–219 (1997)

    Article  CAS  Google Scholar 

  36. Trau, M., Seville, D.A., Aksay, I.A.: Field-induced layering of colloidal crystals. Science. 272(5262), 706–709 (1996)

    Article  CAS  Google Scholar 

  37. Meyers, D.: Surfaces, Interfaces, and Colloids, vol. 2. Wiley-VCH, New York (1999)

    Book  Google Scholar 

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Funding

The authors acknowledge the support of the Grant Agency of the Czech Republic under grant no. 17-08153S. This research was also carried out under the project CEITEC 2020 (LQ1601) with financial support from the Ministry of Education, Youth and Sports of the Czech Republic under the National Sustainability Programme II.

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Authors and Affiliations

  1. CEITEC BUT, Brno University of Technology, Purkynova 123, 612 00, Brno, Czech Republic

    Daniel Drdlik & Katarina Drdlikova

  2. Institute of Materials Science and Engineering, Brno University of Technology, Technicka 2, 616 00, Brno, Czech Republic

    Daniel Drdlik

  3. CEITEC IPM, Institute of Physics of Materials, Academy of Sciences of the Czech Republic, Zizkova 22, 616 62, Brno, Czech Republic

    Zdenek Chlup & Hynek Hadraba

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  1. Daniel Drdlik
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Drdlik, D., Chlup, Z., Hadraba, H. et al. Surface roughness improvement of near net shaped alumina by EPD. J Aust Ceram Soc 56, 721–727 (2020). https://doi.org/10.1007/s41779-019-00390-y

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